Advances in Electron Transfer Chemistry. Volume 6 by P.S. Mariano

By P.S. Mariano

It truly is transparent that electron move chemisty is now some of the most energetic parts of chemical examine. Advances in Electron move Chemistry has been designed to permit scientists who're constructing new wisdom during this quickly increasing zone to explain their most modern examine findings. This quantity will serve these attracted to studying approximately present breakthroughs during this quickly increasing sector of chemical examine.

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Extra resources for Advances in Electron Transfer Chemistry. Volume 6

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Is essentially the 1,1-diarylethylene cation radical in which the unpaired electron and positive charge are located predominantly in the rc system. + does not. Ar,,. ~ ,~_Ar ~ " \\ < \\ 82~ Ar~Ar 83"+ Ar. ~ Ar ~ 84 85 a: Ar = 4-MeOC6H4 Scheme 21. PET Reactions of Cyclopropanes 27 Nanosecond laser flash photolyses of 77a under TCNB- and NMQ+B~44-sensitized conditions provide strong spectroscopic evidence not only for the intermediacy of cation radical 82a "~ in the SET-sensitized photoreactions but also for the trimethylenemethane biradical intermediate 82a~ 41r Laser excitation (308 nm) of TCNB with 77a in acetonitrile gives rise to two intense transient absorptions with maxima at 350 and 500 nm whereas in dichloromethane only the shorter wavelength transient absorption is observed.

2. Indirect Reduc:tion . . . . . . . . . . . 3. Utilization of Sacrificial Anodes . . . . . . . . Cathodic Reduction of Other Polyfluorinated Organic Compounds Application of Electrogenerated Bases to Fluoro-Organic Synthesis . . . . . . . . . . . . . . . Anodic Oxidation of Perfluorinated and Polyfluorinated Organic C o m p o u n d s . . . . . . . . . . . . 1. Anodic Molecular Conversion . . . . . . . . Advances in Electron Transfer Chemistry Volume 6, pages 41-130.

4. Anodic Fluorination of Olefins . . . . . . . . 5. Anodic Fluorination of Carbonyl Compounds 9 . . . 6. Anodic Fluorination of Chalcogeno Compounds . . . 7. Anodic Fluorination of Other Heteroatom Compounds . 8. Anodic Fluorination of Heterocyclic Compounds . . . 9. Anodic g e m - D i f l u o r i n a t i o n . . . . . . . . 10. Indirect Anodic Fluorination . . . . . ..... 11. Chemical Fluorination Using Fluorinating Reagents . . Conclusions . . . . . . .

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